Simple and Cost-effective Extraction of Rare Metals from Industrial Waste

Researchers from Kanazawa University developed a protocol to efficiently purify palladium and silver ions from industrial waste, and convert the ions into pure metallic elements. This will help increase global stock of valuable elements that are widely needed yet in scarce supply.

Kanazawa, Japan – Many rare metals are in scarce supply, yet demand for use in electronics, medical instrumentation, and other purposes continues to increase. As waste, these metals pollute the environment and harm human health. Ideally, we would recycle the metals from waste for reuse. Unfortunately, current recycling methods are some combination of complex, expensive, toxic, wasteful, and ultimately inefficient.

In an upcoming study in Chemical Engineering Journal, researchers from Kanazawa University report a major improvement in recovering silver and palladium ions from aqueous acidic waste. Recovery of the metals in elemental, metallic form is straightforward—simply burn the extraction material and collect the remaining metal after further heating.

The researchers chemically modified ultrasmall particles of cellulose, an abundant and nontoxic biopolymer, to selectively adsorb silver and palladium ions at room temperature. Adsorption was nearly complete at acidic pH with acid concentrations of around 1 to 13 percent by volume. These are reasonable experimental conditions.

"The adsorbent selectively chelated the soft acid silver and palladium cations," explains lead author Foni Biswas. "Of the 11 competing base metals we tested, only copper and lead cations were also adsorbed, but we removed them with ease.”

Maximum metal ion adsorption was fast—e.g., an hour for silver. Maximum adsorption commonly requires many hours with other approaches.

"Intraparticle diffusion did not hinder adsorption, which is an endothermic, spontaneous chemical process," explains senior author Hiroshi Hasegawa. "Maximum metal adsorption capacities—e.g., 11 mmol/g for silver—are substantially higher than that reported in prior research."

After adsorption, the researchers simply incinerated the cellulose particles to obtain elemental silver or palladium powder. Subsequent higher-temperature incineration converted the powder into pellets. Cyanide or other toxic extractants were not required. Spectroscopic analyses indicated that the final metal pellets were in metallic rather than oxide form.

"We removed nearly all of the silver and palladium from real industrial waste samples," says lead author Biswas. "Obtaining pure and elemental metals proceeded as smoothly as in our trial runs."

Palladium and silver are valuable metals yet natural supplies are increasingly limited. Future needs require that we recycle the metals that we already have in a practical manner. The research reported here is an important development that will avoid supply and distribution difficulties that will only increase in the coming years.



Selective recovery of silver and palladium from acidic waste solutions using dithiocarbamate-functionalized cellulose

Journal:Chemical Engineering Journal

Authors: Foni B. Biswas, Ismail M.M. Rahman, Keisuke Nakakubo, Koki Yunoshita, Masaru Endo, Kanji Nagai, Asami S. Mashio, Tsuyoshi Taniguchi, Tatsuya Nishimura, Katsuhiro Maeda, Hiroshi Hasegawa

DOI: 10.1016/j.cej.2020.127225

“This research is partially supported by Grants-in-Aid for Scientific Research (18H03399) from the Japan Society for the Promotion of Science.”